Ibicuruzwa
18-Ikamba-6x; CE No: 17455-13-9
Synonyme: 18-Crownether-6; 18-Ikamba-6 Ether; Etherne Oxide cyclic
Imiti yimiti ya 18-ikamba-6
● Kugaragara / Ibara: Umuhondo muto
. Umuvuduko mwinshi: 4.09e-06mhg kuri 25 ° C.
Gushonga Ingingo: 42-45 ºC (Lit.)
Indangagaciro irohereza: 1.404
Ingingo yo guteka: 395.8 ºC kuri 760 MMHG
● Flash Ingingo: 163.8 ºC
● Zab:55.38000
● Ubucucike: 0.995 G / CM3
● LogP: 0.09960
● Ububiko Temp. :Store kuri 0-5 ° C.
.:Yumva.:hygroscopic
.:Chloroform (1
● Amazi yoroheje.:
● Xlogp3: -0.7
● Hydrogen Bond Abaterankunga kubara: 0
● Hydrogen Bond Kubara: 6
● Bond Kubara: 0
● Misa nyayo: 264.157288848
Atom Atom Arem: 18
● Ingorabahizi: 108
Amakuru ya hefy
● Pictogram (s):
Xn,
Xi
● Kode ya Hazard: XN, XI
Imvugo: 22-36 / 37 / 38-36-20 / 22-20 / 21/22/22
● Amagambo y'umutekano: 26-36-39
Ingirakamaro
Amasomo ya Chimique:Andi masomo -> Ibindi binyabuzima
Inseko ya kanonical:C1coccoccoccoccoccoccoccoccoccoccoccoccoccoccoccoccoccoccoccoccoccocco1
Ikoresha:Icyiciro cyingirakamaro cyohereza umusemburo. 18-Ikamba-6 rikoreshwa nkigice cyiza cyohereza umusemburo kandi nkumukozi utoroshye hamwe na cation zitandukanye. Ifite uruhare muri synthesis ya eather eatle, Diaryl Thioetlems, na Diarylamine yanduye Pluoristide-Alumina na 18-6. Yorohereza ibibazo byo kwikengurwa na potasiyumu Perhananate muri Benzine, ikoreshwa mu kwamarika ibintu kama. Ikoreshwa mu kwihutisha ibintu bitandukanye byo gusimbuza kimwe no kuzamura imbaraga za nocleooFhile nka potasiyumu acetate. Irakoreshwa mubyitwaramo bya alkylilation imbere ya karubanda ya potasiyumu, N-alkylation ya Glutarimide na Succimide hamwe na Dimethylcarbonate. Urugomo rwakozwe na Potasiyumu rwa PATAsisim rukora nk'umusemburo muri cyanosiolation ya Aldehydes, Ketone na Lomeethysilyl cynide (TMSCN). 18-Ikamba-6 rishobora gukoreshwa muri Catalyze N-alkylative yimiryango yubushyuhe na arlylation ya aldehyde.
Intangiriro irambuye
18-ikamba-6ni cyclic ether compound hamwe na formulaimique c12h24o6. Yitwa "18-6-6" Kuberako ikubiyemo impeta ya atome esheshatu za ogisijeni, igakora imiterere imeze nk'ikamba, kandi ifite atome 18 ya karubone muri rusange. Ni ibara ridafite ibara, Crystalline ikomeye ikundwa mubintu bya kama ariko bisakuza mumazi.
Izina "ikamba" rikomoka ku bigo bihuye n'ikamba kubera atome esheshatu za ogisijeni zateguwe mu buryo buzenguruka. Iyi miterere idasanzwe itanga 18-6 imitungo yihariye kandi ituma ikoreshwa cyane muburyo butandukanye.
Kimwe mu bintu by'ingenzi biranga imyaka 18-6 nubushobozi bwayo bworoshye hamwe nicyuma. Atome ya ogisijeni mu mpeta ya ogisijeni irashobora guhuza n'icyuma, nka potasiyumu, sodium, cyangwa calcium, cyangwa calcium, gukora ibintu bifatika. Uyu mutungo ukora ikamba 18-6 uruganda rukoreshwa cyane mumwanya wo guhuza chimie.
Gusaba
Ingorabahizi ya cyuma ni 18-ikamba-6 irashobora kugira porogaramu nyinshi:
Icyiciro cyohereza umusemburo:Kimwe na BenizyMiumhmium chlorimium, 18-ikamba - 6 irashobora kandi gukora nk'igice cyo kohereza icyiciro. Ifasha mu kwimura amoko yishyurwa, nk'icyuma, hagati yicyiciro kidasanzwe, igituma ibintu bitaba bigoye cyangwa bidashoboka. Ikamba rya Crothes Cavity rishobora gukwambura icyuma, kubikemerera kunyura muri membranes cyangwa kwimura hagati yuburyo butandukanye.
Gukuramo icyuma no gutandukana:18-Ikamba-6 rikoreshwa muburyo bwo gukuramo ibicuruzwa kugirango uhitemo gukuramo kandi bitandukanye byicyuma byihariye kuva ku ruvange rugoye. Ubushobozi bwayo bwo guhambira hamwe nicyuma bimwe bituma kwigunga no kwezwa kuri ion bituruka.
Ion amenyekana no kumva:Ingorabahizi y'icyuma na 18-ikamba-6 irashobora gukoreshwa muburyo bwa sensor na ion-guhitamo. Mugushiramo iminsi 18-6 muri sisitemu ya sensor, birashoboka guhitamo kumenya no gupima ion yihariye ishingiye kubwubuhinzi bwabo kubwikamba.
Sisitemu yo gutanga ibiyobyabwenge:Ubushobozi bwa 18-Crown-6 kugirango bukorezwe hamwe na shot yicyuma birashobora gukoreshwa muri sisitemu yo gutanga ibiyobyabwenge. Mugutandukanya icyuma mu ikamba ether cavity, birashoboka kurinda ion yicyuma mugihe cyo gutwara no kubarekura muburyo bugenzurwa kuruhande.
Muri rusange, 18-Ikamba-6 ni uruganda rutandukanye rusanga ibyifuzo muri PHAse Traft, Icyuma gikuramo, ibanga, bimenyekana, no gutanga ibiyobyabwenge. Imiterere idasanzwe ya Ether Imiterere hamwe nuburyo bugoye bugira igikoresho cyingenzi mubice bitandukanye bya chimie nibikoresho byubumenyi.
